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Jacques Huot

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Mechanical activation: cold rolling, ball milling, and cold pressing
Mechanical activation refers to the use of processes like cold rolling, ball milling, and cold pressing to modify the microstructure and surface state of metal hydride alloys to improve their first hydrogenation behavior after air exposure.[1][2] In the Ti0.488Fe0.460Mn0.052 study, all three methods allowed hydrogen absorption by breaking passive oxide layers and introducing defects, with cold pressing delivering the highest hydrogen capacity and ball milling the fastest kinetics, while cold rolling offered effective regeneration with relatively simple processing.[1]
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Ti0.488Fe0.460Mn0.052 TiFe-based hydrogen storage alloy
The Ti0.488Fe0.460Mn0.052 alloy is a TiFe-based intermetallic material engineered for reversible hydrogen storage, produced here by gas atomization to obtain a fine powder microstructure that supports improved first hydrogenation kinetics and capacity after mechanical activation.[1][2] It belongs to the class of interstitial metal hydrides, where hydrogen atoms occupy lattice sites in the TiFe matrix and associated secondary phases, enabling absorption of about 1.5–2 wt.% hydrogen under moderate conditions depending on processing.[2]
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TiFe-based intermetallic metal hydrides
TiFe-based intermetallic hydrides are a class of AB-type alloys where titanium and iron form a host lattice that can reversibly absorb hydrogen to form TiFeH2-type hydrides, offering moderate hydrogen capacity and favorable operating conditions for storage technologies.[2] They are interstitial hydrides in which hydrogen occupies tetrahedral or octahedral lattice sites, and their performance is sensitive to alloying additions (such as Mn and Zr), microstructure, and surface oxidation state.[2]
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UQTR and GKN Hoeganaes show that mechanical treatments can activate gas-atomized Ti0.488Fe0.460Mn0.052 alloy for room-temperature hydrogen storage, cutting energy costs.

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